What is the repeat unit molecular weight for polydimethylsiloxane?

What is the repeat unit molecular weight for polydimethylsiloxane?

1 74.0 Thermo-Physical Properties: Calculated Data

Molecular Weight of Repeat unit g mol 1 74.0
Van-der-Waals Volume VvW mL mol 1 42.6
Molar Volume Vm mL mol 1
Density g mL 1

Is PDMS amorphous?

PDMS is a practically non-entangled semi-crystalline silicone elastomer that melts around 40 C, crystallizes around 90 C and vitrifies upon cooling around 125 C.

What is PDMS material?

Polydimethylsiloxane, called PDMS or dimethicone, is a polymer widely used for the fabrication and prototyping of microfluidic chips. It is a mineral-organic polymer (a structure containing carbon and silicon) of the siloxane family (word derived from silicon, oxygen and alkane).

How is PDMS formed?

Polydimethylsiloxane (PDMS) is the simplest member of the silicone polymer family. It is formed by hydrolyzing Me2SiCl2, which is produced from high-purity SiO2 and CH2Cl2 by the MullerRochow reaction. The term silicone was coined by chemist F. S. Kipping in 1901.

How do I calculate molecular weight?

Sample Molecular Weight Calculation Using the periodic table of the elements to find atomic weights, we find that hydrogen has an atomic weight of 1, and oxygen’s is 16. In order to calculate the molecular weight of one water molecule, we add the contributions from each atom; that is, 2(1) + 1(16) = 18 grams/mole.

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How do you calculate average molecular weight?

To get the number average molecular weight you divide the total weight of the sample by the total number of the molecules.

Is silicone the same as PDMS?

Polydimethylsiloxane (PDMS), also known as dimethylpolysiloxane or dimethicone, belongs to a group of polymeric organosilicon compounds that are commonly referred to as silicones. PDMS is the most widely used silicon-based organic polymer, as its versatility and properties lead to many applications.

How much does PDMS cost?

As for the pricing, for a fair amount of 3 g of the material for each typical microfluidic chip, PDMS will cost around 1 US dollar while EVA has a mere cost of 0.6 cents for each chip and also the higher thermal cost and time-consuming process of curing and bonding of PDMS adds to the cost more than that.

Does PDMS absorb water?

Water vapour diffuses rapidly in silicone polydimethylsiloxane (PDMS) rubber. In a PDMS-salt compound surrounded by water, the water which has entered the rubber is absorbed by the salt particles, creating an osmotic pressure in the rubber.

Is PDMS a liquid?

PDMS are clear transparent odorless liquids, that have good dielectric, damping, surface-active, water-repellent and anti-adhesive, defoaming properties, resistant to low and high temperatures, soluble in most organic solvents.

What is the full form of PDMS?

[1] PDMS (Plant Design Management System) as it is known in the 3D CAD industry, is a customizable, multi-user and multi-discipline, engineer controlled design software package for engineering, design and construction projects in offshore and onshore.

What are the advantages of PDMS?

Advantages of PDMS in biology research Some of them are summarised below: PDMS deformability enables easy connections of leak-proof fluidic connections, integration of fluidic valves through PDMS microchannels and it is used to detect very low forces like biomechanics interactions from cells [4].

Why is PDMS used in microfluidics?

PDMS, as an elastomer, is known for its mold-release properties and ability to replicate features down to the nanoscale, with low shrinkage during cure (around 1%) and excellent elastic properties.

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Does acetone dissolve PDMS?

Diisopropylamine swells PDMS to the greatest extent; solvents such as chloroform, ether, and THF swell the material to a large extent. Solvents such as acetone, 1-propanol, and pyridine swell the material to a small extent. … Dilute sulphuric acid does not etch PDMS away.

Is PDMS brittle?

It’s quite common for the PDMS to become brittle if the curing duration is too long or if the temperature is too high. I found that over-curing the PDMS was the main cause of failure when trying to plasma bond.

What is the formula for moles to grams?

In order to convert the moles of a substance to grams, you will need to multiply the mole value of the substance by its molar mass.

How can I calculate weight?


  1. Weight is a measure of the force of gravity pulling down on an object. It depends on the object’s mass and the acceleration due to gravity, which is 9.8 m/s2 on Earth.
  2. The formula for calculating weight is F = m 9.8 m/s2, where F is the object’s weight in Newtons (N) and m is the object’s mass in kilograms.

What is molecular weight explain with example?

The sum of the atomic masses of all atoms in a molecule, based on a scale in which the atomic masses of hydrogen, carbon, nitrogen, and oxygen are 1, 12, 14, and 16, respectively. For example, the molecular mass of water, which has two atoms of hydrogen and one atom of oxygen, is 18 (i.e., 2 + 16).

What unit is molecular weight?

grams per mole The molecular weight is the mass of one mole of a substance. Usually, the units used for this are grams per mole.

What is Z average molecular weight?

Finally, we can calculate the Z-average molecular weight by introducing yet another term for the weight of each player. This is done by multiplying the number of players of each weight by their weight three times. This average strongly emphasizes the largest members of the team to the exclusion of the smaller players.

What is considered a high molecular weight?

means a polymer that has a number average molecular weight that is greater than or equal to 1,000 g/mol.

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What is the classification of silicone?

Based on the different cure and processing methods, silicone rubber can be classified as solid silicone (HCR) and liquid silicone (LSR). HCR is produced as gummy, high viscosity solid rubber that as partially vulcanzied.

Why is dimethicone bad?

Some people believe that dimethicone is harmful because it’s not natural. Others say that since it forms a barrier, dimethicone seals in oil, sweat, dirt, and other things that can clog pores and lead to acne. However, the amount of dimethicone in face and hair products is generally considered safe.

What are the types of silicones?

Silicone rubbers are man-made polymer materials that have a wide range of industrial and manufacturing applications. The various types of silicone rubbers include room temperature vulcanize, liquid silicone, fluorosilicone and high-consistency rubber.

Which of following polymers is most popular for microfluidics?

Abstract: Using polymer materials to fabricate microfluidic devices provides simple, cost effective, and disposal advantages for both lab-on-a-chip (LOC) devices and micro total analysis systems (TAS). Polydimethylsiloxane (PDMS) elastomer and thermoplastics are the two major polymer materials used in microfluidics.

What are microfluidics used for?

Applications of microfluidics Diagnostic uses of microfluidics include cancer and pathogen detection. Microfluidic devices are used to measure molecular diffusion coefficients, fluid viscosity, pH, and chemical binding coefficients.

How much does it cost to make a microfluidic device?

The microfluidic channels were built with cotton threads and the estimated cost per device was only $0.39. The flow of solutions (1.12 L s 1) is generated spontaneously due to the capillary forces, eliminating the use of any pumping system.

Does rubber degrade in salt water?

Does the material suffer degradation in sea water? Yes, but it will usually be impossible to say how much. This is because most types of silicone rubber are designed for specific applications by adding various fillers to modify the properties of the pure material.

Does silicone absorb moisture?

Moisture and steam resistance Silicone rubber can be immersed in water (cold water, warm water, boiling water) for long periods with water absorption of about 1%, and with virtually no effect on mechanical strength or electrical properties.